4th August 2017: 'Methane clathrate' » 2017 » Mobbsey's Musings » Paul Mobbs/MEI » FRAW

Methane clathrate phase diagram, showing how it exists at different temperatures and pressures

Methane clathrate

The last desperate hope of the fossil fuels industry

Paul Mobbs, Mobbsey's Musings, 4th August 2017

Written for The Free Range Activism Network.

An A3 wall poster (1.8 megabyte PDF file) has been created to accompany this article.

Extreme Energy[1] is a term which encompasses many different forms of 'unconventional' energy resources. From fracking, to tar sands, to some types of renewable energy which take more energy and carbon to produce than they save (mostly plant biomass[2]) – these 'extreme' energy sources represent the last hope of the global energy corporations. Why this is so tells a much greater truth about the global commitment to address climate change.

The transition from 'conventional' oil and gas – produced from free-flowing reservoirs[3] of hydrocarbons underground – to 'unconventional' sources is tied implicitly to the depletion[4] of fossil fuels. As conventional sources are harder to find, and more difficult to produce[5], previously uneconomic unconventional sources of fossil fuel become profitable.

Despite recently low oil prices – the result of global economic stagnation[6] rather than over-supply – the writing's on the wall in terms of where the global energy industry is heading. If depletion doesn't force a change in their business model soon, then the need to drastically cut[7] carbon emissions must do so.

The new extreme – methane clathrate

The world's river systems deposit large quantities of sediment, containing organic matter, onto the ocean floor surrounding the continental land masses. As this material slowly decomposes, with little oxygen available, it produces methane gas.

Some of this methane dissolves into the sea water, or bubbles up from the sea floor to the surface, but under the right conditions it can become trapped within the saturated sediments.

Methane clathrate[8] – also know as methane hydrate, methane ice or natural gas hydrate – is a mixture of methane gas and water. Though it is often called methane 'ice', it doesn't have to be frozen to allow methane to become trapped between the water molecules.

Clathrate is formed when methane becomes wedged between a stable lattice of water molecules. What controls the formation of the clathrate is the combination of temperature and pressure. It can form at low pressure in shallow water at freezing temperatures, but it can also form at higher temperatures under high pressure in deep water.

Methane clathrate is highly sensitive[9] to this temperature/pressure balance. Even a small shift in temperature or pressure can cause the whole clathrate formation to break down, destabilizing the sediments, and causing the methane to erupt as gas into the water column.

Clathrate was first identified in the 1960s, but it wasn't until the end of the 1990s that interest began in clathrate as a source of energy. That was for one key reason – the potential size[10] of the available resource.

The current global natural gas 'reserve' – the amount which we are 90% sure might be produced – is about 186 trillion cubic metres[11] of methane. Current estimates of how much gas might be produced from clathrate vary from 10 to 100 times that figure.

The engineering challenge

Nearly all clathrate is found offshore[12] – which increases the costs of exploring for it. That cost is as nothing compared to the technical challenge of actually recovering the gas, because of its volatile nature.

Thus far there are three proposed methods[13] to get the gas out of the sediment:

Around 30 countries have expressed interest in clathrate research – though few have active programmes today. Given that fossil fuel depletion is a "known, known", many states are desperate to find any new source of natural gas to keep the industrialized economy ticking over.

The US Department of Energy has been giving research grants[14] for clathrate production for a number of years[15]. The focus of the EU has mainly been around the impacts of clathrate[16] production. Canada has also carried out experiments on-shore in the Arctic, though that project was terminated in 2013[17]. And India has had a clathrate research project[18] since the late 1990s.

However, the real movers in this area though are Japan and China:

How can this be economic?

Recent estimates[24] put the cost of clathrate gas production at around $1,000 to $1,750 per thousand cubic metres. Current US wholesale gas prices are around $200 per thousand cubic metres. At five to eight times the current price, how can clathrates be economic?

Both the nations backing research around clathrates, and industry figures projecting the future of fossil fuels, are looking at clathrate production taking off in one or two decades – when fossil fuels become harder to produce.

That's when there's money to be made.

'Extreme' energy isn't just about extreme or difficult to produce energy sources. What supports these ventures is also the 'extreme' frontier of finance and economics.

Speculation, hedging, futures, debt instruments – energy companies raise and spend money through a variety of means, often divorced from the 'real' economy. The energy sector is one of the most 'liberalized' industries, and as a result it is intimately involved with the 'extreme' end of modern-day Machiavellian microeconomics.

Fracking is a good example.

Fracking in the US has survived[25] the low oil prices since 2014 because of its convoluted system of credit and production hedging. Effectively the industry has been kept alive by the gullible banks and Wall Street financiers who have swallowed the industry's lobbying about their success – when the available economic data[26] suggests the complete opposite.

The same is likely to be the case of any nascent clathrate industry.

Let's assume the global clathrate resource is 5,000 trillion cubic metres. The wholesale value of 1,000 cubic metres of gas might vary from $100 to $400. That puts the value of the clathrate resource at $500,000 trillion to $2,000,000 trillion.

If you're a financier, and you get perhaps a tenth of one percent return on that income, you'd stand to make a half to two trillion dollars. That being the case, wouldn't you throw them fifty or a hundred million dollars in order to perfect their technology?

As in the case of fracking, it's the race to be first to create the intellectual property for a 'successful' technology that yields huge profits. Those that follow later tend to lose huge sums instead[27].

Clathrates are climatic 'ecocide'

Of course there has to be a big "but" here, and that's obviously climate change.

Methane clathrate is quite possibly one of the most hazardous uncontrolled feedback mechanisms[28] in the climate system. Climate scientists are concerned[29] because clathrate under ice sheets in the Arctic circle, or submerged off the coast of Siberia and Canada, might suddenly destabilize and release large volumes of methane into the atmosphere – driving global temperatures far higher.

As methane clathrate becomes the new target for gas exploration, it might actually be humans who trigger the release – either through controlled production, or accidentally through production accidents. And perhaps over a much shorter time-frame compared to this natural process.

As recent research reveals, it's only necessary for between 2% and 4% of the methane produced to leak in order for natural gas to have a climate footprint worse than coal[30].

While there might be 10 to 100 times the current gas resource available, the amount of carbon that these deposits contain are far greater.

That disparity occurs because such a small amount of the potential gas 'resource' is available to produce because of the technical limitation – so fugitive emissions[31] could far drastically higher than conventional gas, or even fracking.

In the final analysis, we've already released half-a-trillion tonnes[32] of carbon from fossil fuels since the beginning of the Industrial Revolution, raising temperatures by around 1°C.

Another half-a-trillion[33] will warm the planet to the IPCC's "safe" limit of 2°C.

Depending on[34] which estimates are[35] used, there might be two-and-a-half to three trillion tonnes of carbon locked up in clathrate deposits.

Put more simply, the amount of carbon locked up in clathrates is about the same as the other fossil fuels combined. There can be no solution to the climate change if large-scale clathrate production begins.

The methane clathrate issue highlights the duplicitous nature of the debate over energy and climate. Climate science make it clear that emissions need to be brought near to zero by 2050, or we face a significant global shift in climate. However, the efforts to develop technologies to begin large-scale natural gas production from clathrate in one or two decades demonstrates that states, and the fossil fuel industry, have no serious intent to curtail the future production of fossil fuels.


  1. Extreme Energy Initative, School of Advanced Study, University of London – https://extreme-energy-initiative.blogs.sas.ac.uk/
  2. Biofuels Watchhttp://www.biofuelwatch.org.uk/
  3. Wikipedia: 'Petroleum reservoir'https://en.wikipedia.org/wiki/Petroleum_reservoir
  4. Scientific American: 'The End of Cheap Oil: Global production of conventional oil will begin to decline sooner than most people think, probably within 10 years', Colin J. Campbell and Jean H. Laherrère, March 1998 – http://nature.berkeley.edu/er100/readings/Campbell_1998.pdf
  5. Energy Policy: 'EROI of different fuels and the implications for society', Charles A.S. Hall, Jessica G. Lambert, Stephen B. Balogh, January 2014 – http://www.fraw.org.uk/library/peakoil/hall_2014.pdf
  6. Our Finite World: 'Why energy prices are ultimately headed lower; what the IMF missed', Gail Tverberg, 11th October 2016 – https://ourfiniteworld.com/2016/10/11/why-energy-prices-are-ultimately-headed-lower-what-the-imf-missed/
  7. Generation Foundation: 'Stranded Carbon Assets: Why and How Carbon Risks Should Be Incorporated in Investment Analysis', October 2013 – http://genfound.org/media/pdf-generation-foundation-stranded-carbon-assets-v1.pdf
  8. Wikipedia: 'Methane clathrate'https://en.wikipedia.org/wiki/Methane_clathrate
  9. Wikipedia: 'Gas hydrate stability zone'https://en.wikipedia.org/wiki/Gas_hydrate_stability_zone
  10. BBC News: 'Methane hydrate: Dirty fuel or energy saviour?', Richard Anderson, 17th April 2014 – http://www.bbc.co.uk/news/business-27021610
  11. BP: 'Statistical Review of World Energy 2017', June 2017 – http://www.bp.com/en/global/corporate/energy-economics/statistical-review-of-world-energy.html
  12. U.S. Geological Survey Gas Hydrates Project: 'Database of Worldwide Gas Hydrates'https://woodshole.er.usgs.gov/project-pages/hydrates/database.html
  13. Elements: 'Tapping Methane Hydrates for Unconventional Natural Gas', Carolyn Ruppel, June 2007 – http://www.elementsmagazine.org/archivearticles/e3_3/ruppel.pdf
  14. US DoE Office of Fossil Energy: 'DOE Announces $3.8 Million Investment in New Methane Gas Hydrate Research', 15th September 2016 – https://energy.gov/fe/articles/doe-announces-38-million-investment-new-methane-gas-hydrate-research
  15. The Atlantic: 'Is Methane Hydrate the Energy Source of the Future?', Clare Foran, 24th December 2013 – https://www.theatlantic.com/politics/archive/2013/12/is-methane-hydrate-the-energy-source-of-the-future/444258/
  16. MIDAS: 'Methane from marine gas hydrates', EU MIDAs Project, November 2015 – https://www.eu-midas.net/sites/default/files/downloads/Briefs/MIDAS_hydrates_brief_lowres.pdf
  17. CBC: 'Canada drops out of race to tap methane hydrates', Santiago Ortega Arango, 7th May 2013 – http://www.cbc.ca/news/technology/canada-drops-out-of-race-to-tap-methane-hydrates-1.1358966
  18. Oil & Gas Financial Journal: 'India's gas hydrates', 20th February 2017 – http://www.ogfj.com/articles/print/volume-14/issue-2/features/india-s-gas-hydrates.html
  19. BBC News: 'Japan extracts gas from methane hydrate in world first', 12th March 2013 – http://www.bbc.co.uk/news/business-21752441
  20. US DoE National Energy Technology Laboratory: 'Methane Hydrate Newsletter', October 2013 – https://www.netl.doe.gov/File%20Library/Research/Oil-Gas/methane%20hydrates/MHNews_2013_October.pdf
  21. Sustainability: 'Focus on the Development of Natural Gas Hydrate in China', Zhongfu Tan et al., 28th May 2016 – http://www.mdpi.com/2071-1050/8/6/520/pdf
  22. BBC News: 'China claims breakthrough in mining 'flammable ice'', 19th May 2017 – http://www.bbc.co.uk/news/world-asia-china-39971667
  23. South China Morning Post: 'China taps into cool future for global energy', 18th May 2017 – http://www.scmp.com/news/china/policies-politics/article/2094843/china-taps-cool-future-global-energy
  24. Oil & Gas Financial Journal: 'Challenges of methane hydrates', Darren Spalding and Laura Fox, 7th May 2014 – http://www.ogfj.com/articles/print/volume-11/issue-5/features/challenges-of-methane-hydrates.html
  25. The Ecologist: ' With sub-$60 oil, fracking and tar sands losses threaten the whole financial system', Paul Mobbs, 17th December 2014 – http://www.theecologist.org/News/news_analysis/2679765/with_sub60_oil_fracking_and_tar_sands_losses_threaten_the_whole_financial_system.html
  26. The Economist: 'America's shale firms don't give a frack about financial returns', 25th March 2017 – https://www.economist.com/news/business-and-finance/21719436-exploration-and-production-companies-are-poised-go-another-investment-spree-americas
  27. Reuters: 'BHP chairman says $20 billion investment in shale was a mistake', James Regan, 29th June 2017 – http://uk.reuters.com/article/us-bhp-shale-idUKKBN19K1UZ
  28. Wikipedia: 'Clathrate gun hypothesis'https://en.wikipedia.org/wiki/Clathrate_gun_hypothesis
  29. Nature: 'Past extreme warming events linked to massive carbon release from thawing permafrost', DeConto et al., 5th April 2012 – http://people.earth.yale.edu/sites/default/files/files/Pagani/3_2012%20DeConto_Nature.pdf
  30. Talk Fracking: 'Whitehall's 'Fracking' Science Failure – How the Government has misled Parliament and the public on the climate change impacts of shale oil and gas development in Britain', Paul Mobbs, May 2017 – http://www.fraw.org.uk/mei/archive/themes_fracking.shtml#rptwfsf
  31. Carbon Brief: 'Explained – Fugitive methane emissions from natural gas production', 3rd July 2014 – https://www.carbonbrief.org/explained-fugitive-methane-emissions-from-natural-gas-production
  32. Trillionth Tonnehttp://www.trillionthtonne.org/
  33. Nature: 'Warming caused by cumulative carbon emissions towards the trillionth tonne', Allen et al., 30th April 2009 – http://www.fraw.org.uk/library/climate/allen_2009.pdf
  34. BBC News: 'Ocean methane stocks 'overstated'', Paul Rincon, 17th February 2004 – http://news.bbc.co.uk/1/hi/sci/tech/3493349.stm
  35. Earth and Planetary Science Letters: 'Global inventory of methane clathrate – sensitivity to changes in the deep ocean', Buffett and Archer, October 2004 – http://geosci.uchicago.edu/~archer/reprints/buffett.2004.clathrates.pdf